A short synthesis of nonracemic iodocyclohexene carboxylate fragment for kibdelone and congeners

  • Endoma-Arias M
  • Hudlicky T
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Abstract

A previously reported nonracemic iodocyclohexene carboxylate intermediate used in the asymmetric preparation of kibdelone C and its congeners was prepared in two synthetic steps from the product of microbial dihydroxylation of methyl 2-iodobenzoate. © 2011 Elsevier Ltd. All rights reserved.

Author-supplied keywords

  • Kibdelones
  • Markovnikov hydration
  • Microbial dihydroxylation
  • Nonracemic

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