Silsesquioxane chemistry. 13. Synthesis and structural characterization of a dimeric indasilsesquioxane stabilized by intramolecular hydrogen bonding

  • Lorenz V
  • Fischer A
  • Jacob K
 et al. 
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Abstract

The compound [Cy7Si7O12(OH)InMe]2(2) was prepared in high yield (84%) by reacting the incompletely condensed silsesquioxane derivative CY7Si7O9(OH)3(1) with trimethylindium in toluene solution at 20 °C. The molecular structure of 2 has been determined by X-ray diffraction. In the solid state self-assembly leads to the formation of a dimeric indasilsesquioxane molecule which is stabilized by two intramolecular hydrogen bonds. © 2003 Elsevier Science B.V. All rights reserved.

Author-supplied keywords

  • Hydrogen bonds
  • Indium
  • Metallasilsesquioxanes
  • Silsesquioxanes
  • X-ray structure

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