Solubility of 13 non-polar gases (He, Ne, Ar, Kr, Xe, H2, D2, N2, CH4, C2H4, C2H6, CF4and SF6) in 2-methyltetrahydrofuran at 273.15 to 303.15 K and 101.33 kPa partial pressure of gas

  • Gibanel F
  • López M
  • Royo F
 et al. 
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Abstract

Gibanel, F., López, M.C., Royo, F.M., Pardo, J. and Urieta, J.S., 1993. Solubility of 13 non-polar gases (He, Ne, Ar, Kr, Xe, H2, D2, N2, CH4, C2H4, C2H6, CF4and SF6) in 2-methyltetrahydrofuran at 273.15 to 303.15 K and 101.33 kPa partial pressure of gas. Fluid Phase Equilibria, 87: 285-294. Solubility measurements of several non-polar gases (He, Ne, Ar, Kr, Xe, H2, D2, N2, CH4, C2H4, C2H6, CF4and SF6) in 2-methyltetrahydrofuran in the temperature range 273.15-303.15 K and at 101.33 kPa partial pressure of gas are reported. Standard changes in thermodynamic functions for the solution process (Gibbs energies, enthalpies and entropies) at 298.15 K are evaluated from experimental solubilities and their variation with temperature. Lennard-Jones 6,12 pair potential parameters and the temperature dependence on effective hard-sphere diameter for 2-methyltetrahydrofuran are estimated using the scaled particle theory applied to gas-liquid solubility. Experimental solubilities as mole fractions are compared with calculated values using this theory. © 1993.

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Authors

  • F. Gibanel

  • M. C. López

  • F. M. Royo

  • J. Pardo

  • J. S. Urieta

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