Stereocontrolled access to carba-C-disaccharides via functionalized dienylsilanes

  • Angelaud R
  • Landais Y
  • Parra-Rapado L
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Abstract

We report here the total synthesis of a class of C1 → C6 Carba-C-disaccharide, formed by the association between a 2-deoxyglucose as the sugar unit and a pseudo-pyranose or a pseudo-furanose as the carba-sugar moiety. The carba-sugar fragments were assembled from the corresponding dienylsilanes through a dihydroxylation-cyclopropanation sequence.

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Authors

  • Rémy Angelaud

  • Yannick Landais

  • Liliana Parra-Rapado

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