We report here the total synthesis of a class of C1 → C6 Carba-C-disaccharide, formed by the association between a 2-deoxyglucose as the sugar unit and a pseudo-pyranose or a pseudo-furanose as the carba-sugar moiety. The carba-sugar fragments were assembled from the corresponding dienylsilanes through a dihydroxylation-cyclopropanation sequence.
Angelaud, R., Landais, Y., & Parra-Rapado, L. (1997). Stereocontrolled access to carba-C-disaccharides via functionalized dienylsilanes. Tetrahedron Letters, 38(51), 8845–8848. https://doi.org/10.1016/S0040-4039(97)10389-6