Stereocontrolled synthesis of all eight stereoisomers of the putative anti-androgen cyoctol

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Abstract

All eight stereoisomers (1-4 and enantiomers) of the putative anti-androgen cyoctol have been synthesized along stereochemically unambiguous routes. The biological tests of all isomers indicated that cyoctol is not an anti-androgen, contrary to the patent literature. All eight stereoisomers of the putative anti-androgen cyoctol have been prepared and tested biologically. © 2004 Elsevier Ltd. All rights reserved.

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Mulzer, J., Kaselow, U., Graske, K. D., Kühne, H., Sieg, A., & Martin, H. J. (2004). Stereocontrolled synthesis of all eight stereoisomers of the putative anti-androgen cyoctol. In Tetrahedron (Vol. 60, pp. 9599–9614). https://doi.org/10.1016/j.tet.2004.06.143

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