Stereoselective synthesis of Sch 642305, an inhibitor of bacterial DNA primase

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Abstract

Sch 642305 is a fungal nonanolide, which inhibits bacterial DNA primase and HIV-1 Tat transactivation. The enantioselective synthesis of Sch 642305 was succeeded starting from useful chiral building block via stereoselective dianion alkylation of β-ketosulfoxide and lactonization. © 2005 Elsevier Ltd. All rights reserved.

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Ishigami, K., Katsuta, R., & Watanabe, H. (2006). Stereoselective synthesis of Sch 642305, an inhibitor of bacterial DNA primase. Tetrahedron, 62(10), 2224–2230. https://doi.org/10.1016/j.tet.2005.12.009

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