Structure et proprietes chimiques du complexe Cp(DPPE)FeCOPh. Preparation de complexes carbeniques

  • Felkin H
  • Meunier B
  • Pascard C
 et al. 
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Cp(DPPE)Fe(COPh) (A) can be prepared either by reaction of benzoyl chloride with the inorganic Grignard reagent Cp(DPPE)FeMgBr or by irradiation of Cp(CO)2Fe(COPh) in the presence of DPPE. Complex A Shows a particularly low carbonyl absorption in the infrared spectrum: 1510 cm-1. The crystal structure determination shows a distorted geometry for the benzoyl group. A is a precursor for carbene complexes which do not contain carbonyl ligands. © 1977.

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  • H. Felkin

  • B. Meunier

  • C. Pascard

  • T. Prange

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