Studies on the radii dependent lanthanide self-assembly coordination behaviors of a flexible dicarboxylate ligand

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Abstract

Two new lanthanide coordination polymers {[Eu2(BDOA)3(H2O)2] · 2H2O}n (1) and {[Er2(BDOA)3(H2O)2]}n (2) were synthesized by treating the corresponding lanthanide(III) chloride and a flexible ligand benzene-1,4-dioxyacetic acid (H2-BDOA). Single-crystal X-ray studies reveal that the ligand BDOA2- adopts different coordination modes in these complexes. Self-assemblies between these bridging ligands and metal ions result in different three-dimensional coordination polymers. The luminescence property of 1 was investigated in the solid state at room temperature. © 2006 Elsevier B.V. All rights reserved.

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Li, X. F., Han, Z. B., Cheng, X. N., & Chen, X. M. (2006). Studies on the radii dependent lanthanide self-assembly coordination behaviors of a flexible dicarboxylate ligand. Inorganic Chemistry Communications, 9(11), 1091–1095. https://doi.org/10.1016/j.inoche.2006.07.009

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