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The synthesis and structural characterization of tetra(1H, 1H, 2H, 2H-polyfluoroalkyl)silaneswith the same or different chain lengths CnF2n+1 linked to Si (1≤n≤6) is reported. When the synthesis was effected from chlorosilanes and fluorinated organomagnesiumor organolithium reagents, the trialkylsilanes were obtained. The last fluorinated chainwas introduced either via a fluoroalkyllithium reagent or by hydrosilylation of thetrialkylsilanes. Some properties and characterization by 1H, 19F and 29Si NMR spectroscopy of the1H, 1H, 2H, 2H-polyfluoroalkylsilanes are described. © 1993.




Boutevin, B., Guida-Pietrasanta, F., Ratsimihety, A., Caporiccio, G., & Gornowicz, G. (1993). Study of the alkylation of chlorosilanes. Part I. Synthesis of tetra(1H, 1H, 2H, 2H-polyfluoroalkyl)silanes. Journal of Fluorine Chemistry, 60(2–3), 211–223. https://doi.org/10.1016/S0022-1139(00)80035-4

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