Syntheses of allyldihydroquinolines: Indium-mediated allylations of EEDQ in the presence of acetic acid

  • Lee J
  • Kweon J
  • Yoon C
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Abstract

Indium-mediated allylations of EEDQ with various allyl bromides in the presence of 1.2 equiv. of acetic acid at rt gave the corresponding allylated dihydroquinolines with high α selectivities in high yields. The allylations of EEDQ with limited allyltins and allylsilane in the presence of BF3·Et2O at rt gave the corresponding allylated products in high yields. © 2002 Elsevier Science Ltd. All rights reserved.

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Authors

  • Ji Hee Lee

  • Jin Sun Kweon

  • Cheol Min Yoon

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