Syntheses and structures of two hydrogen bonding frameworks with bis(triazole) and 1,2,4,5-benzenetetracarboxylate

  • Yang Y
  • Wang H
  • Liang N
 et al. 
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Abstract

The reaction of 4-[3-(1,2,4-triazolyl)-1,2,4-triazole] (trtr), 1,2,4,5-benzenetetracarboxylic acid (H4btec), with Co(II) and Cu(II) salts yields two complexes [Co(trtr)2(H2O)4](H2btec)(H2O)4(1) and {[Cu(trtr)2(H2btec)(H2O)](H2O)6}n(2). 1 is comprised of monomeric [Co(trtr)2(H2O)4]2+cation, H2btec2-anion, and lattice water molecules. The structure of 2 is an one-dimensional chain. 1 further forms a three-dimensional hydrogen bonding network. However, 2 constructs a two-dimensional hydrogen bonding network. © 2009 Elsevier B.V. All rights reserved.

Author-supplied keywords

  • Benzenetetracarobxylate
  • Bis(triazole) ligand
  • Crystal structure
  • Hydrogen bonding network

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