Synthesis of (μ-alkoxo)bis(μ-carboxylato)diruthenium complex having porphyrin moieties as a potential photo-harvesting functionality

  • Tanihara N
  • Obata M
  • Harada M
 et al. 
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Abstract

The ligand substitution reaction of K[Ru2(dhpta)(μ-O2CCH3)2] (H5dhpta = 1,3-diamino-2-hydroxypropanetetraacetic acid) with zinc 5-(4-carboxylphenyl)-10,15,20-triphenylporphyrin (ZnTPP-p-COOH) afforded a diruthenium complex having porphyrin moieties, K[Ru2(dhpta)(μ-O2C-p-ZnTPP)2]. This product was characterized by UV-Vis and1H NMR spectroscopy, and EXAFS analysis. © 2003 Elsevier Science B.V. All rights reserved.

Author-supplied keywords

  • EXAFS analysis
  • Porphyrin derivatives
  • Ruthenium complex

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Authors

  • Norie Tanihara

  • Makoto Obata

  • Masafumi Harada

  • Yuji Mikata

  • Akihisa Hamazawa

  • Isamu Kinoshita

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