Synthesis of [5.5.5.5]fenestranes by pd-catalyzed carbonylation-cyclisation

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Abstract

Pd-catalyzed reaction of 3-acetoxy-8-butenyl- (9) and 8-but-3-inyl-bicyclo[3.3.0]oct-1-ene (11) with CO in CH3COOH lead via double annulation to all-cis[5.5.5.5]fenestranes. © 1992.

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Keese, R., Guidetti-Grept, R., & Herzog, B. (1992). Synthesis of [5.5.5.5]fenestranes by pd-catalyzed carbonylation-cyclisation. Tetrahedron Letters, 33(9), 1207–1210. https://doi.org/10.1016/S0040-4039(00)91897-5

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