Four new [RuCl2(perimidine)(p-cymene)] complexes have been prepared and characterized. Upon reaction with 1,1-diphenylprop-2-yn-1-ol they generate catalyst precursors, which perform the cycloisomerization of diallyltosylamide into N-tosyl-α-methylenepyrrolidine. © 2005 Elsevier B.V. All rights reserved.
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