Synthesis and characterization of asymmetric C,N-cyclometallated complexes of Mo(II). X-ray crystal structures of [η5-C5H5)MoC6H2-(OCH2O)-2,3-CH2NMe2-6(I)(NO)] and [(η5-C5H5)MoS-C6H4CH(Me)NMe2-2(I)(NO)]

7Citations
Citations of this article
1Readers
Mendeley users who have this article in their library.
Get full text

Abstract

The reaction of (η5-C5H5)Mo(μ-I)(I)(NO)2] with the Hg derivatives of substituted N,N-dimethylbenzylamines [Hg(Q dmba)2] (HQ = substituted N,N-dimethylbenzylamine affords the organomolybdenum complexes [(η5-C5H5Mo(Qdmba)(I)(NO)] (2a-2e) in nearly quantitative yield as a racemic mixture of both enantiomers. When the reaction is carried out with HgS-C6H4C(H)(Me)NMe2)2, a 1 : 1 mixture of both diastereoisomers [(η5-C5H5)MoS-C6H4C(H)(Me)NMe2-2(I)(NO)] (2f-2g) is obtained. The resolution of this mixture can be accomplished by fractional crystallization in CH2Cl2/hexane. The X-ray crystal structure of the complexes (SPY-5-15-A, C)-[η5-C5H5)MoC6H2-(OCH2O)-2,3-CH2NMe2-6(I)(NO)] (2b) and (SPY-5-15-C)-[(η5-C5H5)MoS-C6H4C(H)(Me)NMe2-2(I)(NO)](2f) are reported. © 1995.

Cite

CITATION STYLE

APA

Pfeffer, M., Urriolabeitia, E. P., de Cian, A., & Fischer, J. (1995). Synthesis and characterization of asymmetric C,N-cyclometallated complexes of Mo(II). X-ray crystal structures of [η5-C5H5)MoC6H2-(OCH2O)-2,3-CH2NMe2-6(I)(NO)] and [(η5-C5H5)MoS-C6H4CH(Me)NMe2-2(I)(NO)]. Journal of Organometallic Chemistry, 494(1–2), 187–193. https://doi.org/10.1016/0022-328X(95)05429-S

Register to see more suggestions

Mendeley helps you to discover research relevant for your work.

Already have an account?

Save time finding and organizing research with Mendeley

Sign up for free