[MoO2(butanediolato)2· 2(butanediol)] reacts with the Schiff base SAIH in methanol to afford the title complex which has been characterized by elemental analysis, IR and electronic spectroscopy and TGA. The single crystal X-ray structure of the complex reveals that the molecule possesses the usual cis-MoO22+ core and that the ligand SAIH is present as a tridentate donor coordinating through ONO, which forms one five-membered ring and one six-membered ring. The sixth coordination site around Mo is occupied by a methanol molecule, giving the molybdenum a distorted octahedral configuration. © 1992.
CITATION STYLE
Ying-Li, Z., Xue-Xiang, X., & Xin, W. (1992). Synthesis and characterization of cis-dioxomolybdenum(VI) complex of the Schiff base salicylaldehyde isonicoyhydrazone (SAIH) and the crystal structure of [MoO2(o-C6H4CHNNCOC5H4N)CH3OH]. Polyhedron, 11(4), 415–418. https://doi.org/10.1016/S0277-5387(00)83195-2
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