Synthesis of cordiaquinone J and K via B-alkyl Suzuki-Miyaura coupling as a key step and determination of the absolute configuration of natural products

  • Yajima A
  • Saitou F
  • Sekimoto M
 et al. 
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Abstract

A versatile methodology for the synthesis of various terpenoids via B-alkyl Suzuki-Miyaura coupling as a key step is established. Synthesis of cordiaquinone J and K, new antifungal and larvicidal meroterpenoids, was achieved by using this methodology. The absolute configurations of cordiaquinone J and K were confirmed by the synthesis. © 2005 Elsevier Ltd. All rights reserved.

Author-supplied keywords

  • Absolute configuration
  • B-Alkyl Suzuki-Miyaura coupling
  • Cordiaquinones
  • Synthesis

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Authors

  • Arata Yajima

  • Fumihiro Saitou

  • Mayu Sekimoto

  • Shoichiro Maetoko

  • Tomoo Nukada

  • Goro Yabuta

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