Synthesis of cordiaquinone J and K via B-alkyl Suzuki-Miyaura coupling as a key step and determination of the absolute configuration of natural products

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Abstract

A versatile methodology for the synthesis of various terpenoids via B-alkyl Suzuki-Miyaura coupling as a key step is established. Synthesis of cordiaquinone J and K, new antifungal and larvicidal meroterpenoids, was achieved by using this methodology. The absolute configurations of cordiaquinone J and K were confirmed by the synthesis. © 2005 Elsevier Ltd. All rights reserved.

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Yajima, A., Saitou, F., Sekimoto, M., Maetoko, S., Nukada, T., & Yabuta, G. (2005). Synthesis of cordiaquinone J and K via B-alkyl Suzuki-Miyaura coupling as a key step and determination of the absolute configuration of natural products. Tetrahedron, 61(38), 9164–9172. https://doi.org/10.1016/j.tet.2005.06.115

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