Synthesis of (E)-nitro olefins by isomerisation of (Z)-nitro olefins with polymer-supported triphenylphosphine

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Abstract

We have found that (Z)-nitro olefins or mixtures of (E)- and (Z)-compounds can be converted to the pure (E)-isomers by treatment with catalytic amounts of triethylamine or polymer-bound triphenylphosphine, respectively.

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Stanetty, P., & Kremslehner, M. (1998). Synthesis of (E)-nitro olefins by isomerisation of (Z)-nitro olefins with polymer-supported triphenylphosphine. Tetrahedron Letters, 39(8), 811–812. https://doi.org/10.1016/S0040-4039(97)10789-4

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