Synthesis and kinetic cyclisation of quinine-derived oligomers

  • Rowan S
  • Brady P
  • Sanders J
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Abstract

The synthesis and kinetic cyclisations of a series of linear quinine oligomers are described. The distribution of cyclic oligomers is different from that observed in the corresponding thermodynamic cyclisation: cyclic tetramer is observed in the kinetic cyclisations, indicating that its absence under thermodynamic conditions is not due to any kinetic barrier to its formation.

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Authors

  • Stuart J. Rowan

  • Paul A. Brady

  • Jeremy K.M. Sanders

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