Synthesis and kinetic cyclisation of quinine-derived oligomers

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Abstract

The synthesis and kinetic cyclisations of a series of linear quinine oligomers are described. The distribution of cyclic oligomers is different from that observed in the corresponding thermodynamic cyclisation: cyclic tetramer is observed in the kinetic cyclisations, indicating that its absence under thermodynamic conditions is not due to any kinetic barrier to its formation.

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Rowan, S. J., Brady, P. A., & Sanders, J. K. M. (1996). Synthesis and kinetic cyclisation of quinine-derived oligomers. Tetrahedron Letters, 37(33), 6013–6016. https://doi.org/10.1016/0040-4039(96)01263-4

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