Synthesis, magnetic properties and molecular structure of CuLCl2, where L = 2-aminomethylpyridine (amp) and 2,2′-aminoethylpyridine (aep). One-dimensional antiferromagnetic interactions in Cu(amp)Cl2

24Citations
Citations of this article
3Readers
Mendeley users who have this article in their library.
Get full text

Abstract

The synthesis, magnetic properties and molecular structure of two copper(II) chloride complexes of aminoalkylpyridines are discussed. The X-ray crystal structure of Cu(amp)Cl2(amp = 2-aminomethyl-pyridine) shows the compound crystallizes as a one dimensional chain with one chlorine non-bridging and the other chlorine triply bridging. The magnetic data are successfully analyzed with the Bonner-Fisher one dimensional magnetic chain model with the resulting parameters: g = 2.06, J/k = 7.11 K, zJ′/k = -0.69 K. The analogous complex Cu(aep)Cl2(aep = 2-2′-aminoethylpyridine) is reinvestigated using the dimer equation corrected with the molecular field approximation. The resulting parameters are g = 2.05, J/k = -3.83 K, zJ′/k = -0.12 K. Crystal data for CuC6H8N2Cl2: monoclinic, a = 7.932(2) Å, b = 6.257(1) Å, c = 9.435(2) Å, β = 112.97(2)°, V = 431.1(3) Å3, Z = 2, space group P21/m. © 1985.

Cite

CITATION STYLE

APA

O’Connor, C. J., Eduok, E. E., Fronczek, F. R., & Kahn, O. (1985). Synthesis, magnetic properties and molecular structure of CuLCl2, where L = 2-aminomethylpyridine (amp) and 2,2′-aminoethylpyridine (aep). One-dimensional antiferromagnetic interactions in Cu(amp)Cl2. Inorganica Chimica Acta, 105(2), 107–113. https://doi.org/10.1016/S0020-1693(00)90548-6

Register to see more suggestions

Mendeley helps you to discover research relevant for your work.

Already have an account?

Save time finding and organizing research with Mendeley

Sign up for free