Synthesis of statine and its analogues by homogeneous asymmetric hydrogenation

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Abstract

Diastereoselective hydrogenation of N-protected γ-amino β-keto esters catalyzed by BINAP--Ru(II) complexes provides an efficient entry to the statine series with high enantiomeric purities. © 1988.

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Nishi, T., Kitamura, M., Ohkuma, T., & Noyori, R. (1988). Synthesis of statine and its analogues by homogeneous asymmetric hydrogenation. Tetrahedron Letters, 29(48), 6327–6330. https://doi.org/10.1016/S0040-4039(00)82338-2

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