Synthesis and structure of C2-symmetric N-heterocyclic carbene complexes of palladium

  • Marshall C
  • Ward M
  • Harrison W
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Abstract

The first 9- and 11-membered cis and trans C2-symmetric benzimidazol-2-ylidene palladium(II) complexes based on a trans-2,2-dimethyl-1, 3-dioxalane backbone were synthesised and the configuration of the complexes was elucidated via NMR and X-ray crystallography. © 2004 Elsevier Ltd. All rights reserved.

Author-supplied keywords

  • Benzimidazol-2-ylidene palladium(II) complexes
  • C2-symmetric
  • Carbene

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Authors

  • Colin Marshall

  • Mark F. Ward

  • William T.A. Harrison

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