Synthesis and structure of highly polarised double-bond compounds derived from S-proline

  • Aitken A
  • Ali K
  • De Elena N
 et al. 
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Abstract

Reaction of the chiral iminium salt 3 with stabilised carbanions gives the compounds 4-9 containing a highly polarised double bond. The extent of this polarisation is determined by variable temperature1H NMR studies, comparison of13C NMR chemical shifts and an X-ray structure determination. © 2000 Elsevier Science Ltd.

Author-supplied keywords

  • Enamino esters
  • Iminium salts
  • Thiazolidines
  • X-ray crystal structures

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