Synthetic studies on bradykinin antagonist martinellines: Construction of a pyrrolo[3,2-c]quinoline skeleton using silicon-tether RCM reaction and allylic amination

  • Hara O
  • Sugimoto K
  • Hamada Y
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The pyrrolo[3,2-c]quinoline consisting of a core structure of martinellines, the first naturally occurring heterocycle, was prepared through silicon-tether ring-closing metathesis reaction and intramolecular allylic amination as key steps. Graphical Abstract. © 2004 Elsevier Ltd. All rights reserved.

Author-supplied keywords

  • Cross-metathesis
  • Intramolecular allylic amination
  • Martinelline
  • Pyrrolo[3,2-c]quinoline
  • Silicon-tether ring-closing metathesis

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  • Osamu Hara

  • Kazuhiko Sugimoto

  • Yasumasa Hamada

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