Synthetic studies on bradykinin antagonist martinellines: Construction of a pyrrolo[3,2-c]quinoline skeleton using silicon-tether RCM reaction and allylic amination

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Abstract

The pyrrolo[3,2-c]quinoline consisting of a core structure of martinellines, the first naturally occurring heterocycle, was prepared through silicon-tether ring-closing metathesis reaction and intramolecular allylic amination as key steps. Graphical Abstract. © 2004 Elsevier Ltd. All rights reserved.

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Hara, O., Sugimoto, K., & Hamada, Y. (2004). Synthetic studies on bradykinin antagonist martinellines: Construction of a pyrrolo[3,2-c]quinoline skeleton using silicon-tether RCM reaction and allylic amination. Tetrahedron, 60(42), 9381–9390. https://doi.org/10.1016/j.tet.2004.08.014

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