Systematics of diatomic molecular transition moments: Encouraging progress

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Abstract

Literature absolute transition moments for A-X (0-0) bands have been used to obtain "best" values of Refor some 30 molecules. For isoelectronic sequences, Revs Z (heavy)/Z (light) is steeper at abscissae near 1.0 than a larger abscissae, contrary to expectation. For isovalent sequences, e.g. CH, SiH, Re(WY) is in each lower (average, 53%) than Re(WX). Suggestions will emerge for measurements which would be helpful in furthering diatomic molecular transition moment systematics. © 1975.

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Hefferlin, R. (1975). Systematics of diatomic molecular transition moments: Encouraging progress. Journal of Quantitative Spectroscopy and Radiative Transfer, 15(10), 925–927. https://doi.org/10.1016/0022-4073(75)90135-1

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