On the use of (TMS)3CH as novel tin-free radical reducing agent

  • Perchyonok V
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Abstract

(TMS)3CH is an efficient free radical reducing agent. Debromination, deiodation, dechlorination as well as decarboxylation of Barton and Kim esters can proceed smoothly using this tin-free reducing agent. Rate constants for hydrogen atom abstraction from TMS3CH by primary radicals were also determined. © 2006.

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Authors

  • V. Tamara Perchyonok

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