On the use of (TMS)3CH as novel tin-free radical reducing agent

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Abstract

(TMS)3CH is an efficient free radical reducing agent. Debromination, deiodation, dechlorination as well as decarboxylation of Barton and Kim esters can proceed smoothly using this tin-free reducing agent. Rate constants for hydrogen atom abstraction from TMS3CH by primary radicals were also determined. © 2006.

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Perchyonok, V. T. (2006). On the use of (TMS)3CH as novel tin-free radical reducing agent. Tetrahedron Letters, 47(29), 5163–5165. https://doi.org/10.1016/j.tetlet.2006.05.068

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