Transition metal framework substitutions in sodalites

  • Vaughan D
  • Strohmaier K
  • Pickering I
 et al. 
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Abstract

Syntheses of sodalites have been made using different anions, showing anion structure direction to sodalite or cancrinite. Substitution of framework cations has similar structure direction with Fe3+and Cr3+promoting sodalite crystallization. Characterization of sodalites made at different Fe/Al ratios shows that at low levels of substitution most of the Fe3+enters the framework sites (

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Authors

  • D. E.W. Vaughan

  • K. G. Strohmaier

  • I. J. Pickering

  • G. N. George

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