Transport properties of solid state crown ether channel systems

18Citations
Citations of this article
3Readers
Mendeley users who have this article in their library.
Get full text

Abstract

Single crystals of [(H2O)⊂(DB18C6)(μ2-H2O)2/2][(H3O)⊂(DB18C6)(μ2-H2O)2/2]I31 were shown to possess ideally stacked crown ether molecules which form channels running in one direction through the solid state structure. By immersion of single crystals of 1 into NaOH, ion exchange takes place to yield the compound [(Na)⊂(DB18C6)(μ2-H2O)2/2][(Na)⊂(DB18C6)(μ2-OH)2/2]I32, with slightly but significantly different cell parameters. Both compounds were tested for transport properties through these channels by using two different devices, one for water transport, the other for NaOH transport, through single crystals of 1 and 2, respectively. The results indicate that transport can take place via a hopping mechanism. © 2007 Elsevier Masson SAS. All rights reserved.

Cite

CITATION STYLE

APA

Fromm, K. M., & Bergougnant, R. D. (2007). Transport properties of solid state crown ether channel systems. Solid State Sciences, 9(7), 580–587. https://doi.org/10.1016/j.solidstatesciences.2007.04.012

Register to see more suggestions

Mendeley helps you to discover research relevant for your work.

Already have an account?

Save time finding and organizing research with Mendeley

Sign up for free