Vibrational analysis of Cs + CO coadsorbed on Ru(0001)

  • He P
  • Xu Y
  • Jacobi K
  • 1


    Mendeley users who have this article in their library.
  • 11


    Citations of this article.


On the Ru(0001) surface Cs and CO form a very well ordered (Cs + CO)-(2 × 2) compound layer whose structure was determined recently (Cs on-top, CO in 3-fold sites). Here we present a vibrational analysis of the same system using high-resolution electron energy loss spectroscopy (HREELS), thermal desorption spectroscopy (TDS), and low-energy electron diffraction (LEED). Two C-O stretch frequencies are observed depending on whether there are one or two CO molecules in the 2 × 2 cell. Two CO-Ru stretch modes are observed for the first time and are assigned to adsorption in the hcp and fee hollow sites within the 2 × 2 cell. They are very weak in intensity which is attributed to the threefold-hollow site and some screening in the 2D compound. With CO adsorption a change of the electronic structure is observed: the adlayer loses metallicity and the Cs-Ru stretch becomes visible. Strong changes of the Cs-Ru stretch energies are observed with CO coverage.

Author-supplied keywords

  • Carbon monoxide
  • Cesium
  • Chemisorption
  • Compound formation
  • Electron energy loss spectroscopy
  • Low index single crystal surfaces

Get free article suggestions today

Mendeley saves you time finding and organizing research

Sign up here
Already have an account ?Sign in

Find this document


  • Peimo He

  • Yabo Xu

  • K. Jacobi

Cite this document

Choose a citation style from the tabs below

Save time finding and organizing research with Mendeley

Sign up for free