Yb(OTf)3-TMSOTf-catalyzed reactions of acylzirconocene chloride to imines

  • Kakuuchi A
  • Taguchi T
  • Hanzawa Y
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Abstract

Direct access of α-amino ketone derivatives through reactions of acylzirconocene chlorides with derivatives of N-benzylideneaniline, in which acylzirconocene chlorides react as an 'unmasked' acyl anion donor, was carried out for the first time under Yb(OTf)3-TMSOTf-catalyzed conditions. © 2001 Elsevier Science Ltd.

Author-supplied keywords

  • Acyl anion
  • Acylzirconocene chloride
  • Imine derivatives
  • Yb(OTf)3-TMSOTf-catalyst

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Authors

  • Akito Kakuuchi

  • Takeo Taguchi

  • Yuji Hanzawa

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