A calix[4]arene derived dibenzonitrile receptor modified at its "lower rim" by a polymerizable group

  • Tabakci M
  • Memon S
  • Sap B
 et al. 
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Abstract

The present work describes the synthesis of a new monomeric dibenzonitrile derivative of p-tert-butylcalix[4]arene containing a polymerizable group at its lower rim. This monomer with an acryl amide group has been copolymerized with styrene yielding a linear polymer with pendant calixarene groups. Extraction studies with this monomer and its copolymer show no selectivity for metal cations. Nevertheless, dibenzonitrile groups with calixarene moiety provide a suitable binding site for transferring metal salt (NaHCr2O7) as an ion-pair.

Author-supplied keywords

  • Calixarene
  • Copolymer
  • Dichromate anions
  • Solvent extraction
  • Transition metal

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