Chiral recognition of hybrid metal oxide by peptides

  • Micoine K
  • Hasenknopf B
  • Thorimbert S
 et al. 
  • 1

    Readers

    Mendeley users who have this article in their library.
  • N/A

    Citations

    Citations of this article.

Abstract

Resolution of gram quantities of a subtly chiral polyoxometalate (POM; the chirality originates from substitution of one metal in the nanosized framework) is possible by reaction with small peptides. Functionalizable acyl polyoxotungstate (TBA)(6)[alpha(1)-P(2)W(17)O(61){SnCH(2)CH(2)C(=O)}] (see picture) can be resolved by kinetic resolution. This approach paves the way for applications of chiral POMs ranging from asymmetric catalysis to their bioactivity.

Author-supplied keywords

  • Nanoparticles
  • Oxides
  • Peptides
  • Polymers
  • Stereoisomerism
  • Tungsten Compounds

Get free article suggestions today

Mendeley saves you time finding and organizing research

Sign up here
Already have an account ?Sign in

Find this document

Authors

  • K Micoine

  • B Hasenknopf

  • S Thorimbert

  • E Lacôte

  • M Malacria

Cite this document

Choose a citation style from the tabs below

Save time finding and organizing research with Mendeley

Sign up for free