Core-Shell-Corona Micelles with a Responsive Shell

  • Gohy J
  • Willet N
  • Varshney S
  • et al.
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Abstract

A reactor for the synthesis of gold nanoparticles (see atomic force microscopy image) is one of the uses of a poly(styrene)-block-poly(2-vinylpyridine)-block-poly(ethylene oxide) triblock copolymer (PS-b-P2VP-b-PEO) which forms core-shell-corona micelles in water. Very low polydispersity spherical micelles are observed that consist of a PS core surrounded by a pH-sensitive P2VP shell and a corona of PEO chains end-capped by a hydroxyl group. The corona can act as a site for attaching responsive or sensing molecules.

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Gohy, J.-F., Willet, N., Varshney, S., Zhang, J.-X., & Jérôme, R. (2001). Core-Shell-Corona Micelles with a Responsive Shell. Angewandte Chemie International Edition, 40(17), 3214–3216. https://doi.org/10.1002/1521-3773(20010903)40:17<3214::aid-anie3214>3.0.co;2-f

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