Covalent surface modification of a metal–organic framework: selective surface engineering via CuI-catalyzed Huisgen cycloaddition

  • Gadzikwa T
  • Lu G
  • Stern C
 et al. 
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Abstract

A Zn-cornered, mixed-ligand, metal-organic framework (MOF) bearing TMS-protected acetylenes has been constructed and its surface decorated with organic molecules via'click chemistry', in a demonstration of selective post-synthesis functionalization.

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Authors

  • Tendai Gadzikwa

  • Guang Lu

  • Charlotte L. Stern

  • Scott R. Wilson

  • Joseph T. Hupp

  • SonBinh T. Nguyen

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