Covalent surface modification of a metal-organic framework: Selective surface engineering via CuI-catalyzed Huisgen cycloaddition

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Abstract

A Zn-cornered, mixed-ligand, metal-organic framework (MOF) bearing TMS-protected acetylenes has been constructed and its surface decorated with organic molecules via'click chemistry', in a demonstration of selective post-synthesis functionalization. © The Royal Society of Chemistry.

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Gadzikwa, T., Lu, G., Stern, C. L., Wilson, S. R., Hupp, J. T., & Nguyen, S. T. (2008). Covalent surface modification of a metal-organic framework: Selective surface engineering via CuI-catalyzed Huisgen cycloaddition. Chemical Communications, (43), 5493–5495. https://doi.org/10.1039/b805101a

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