Cp* iridium complexes give catalytic alkane hydroxylation with retention of stereochemistry

  • Zhou M
  • Schley N
  • Crabtree R
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Abstract

A series of Cp*Ir complexes can catalyze C-H oxidn., with ceric ammonium nitrate as the terminal oxidant and water as the source of oxygen. Remarkably the hydroxylation of cis-decalin and 1,4-dimethylcyclohexane proceeds with retention of stereochem. With H2O18, cis-decalin oxidn. gave 18O incorporation into the product cis-decalol. [on SciFinder(R)]

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Authors

  • Meng Zhou

  • Nathan D. Schley

  • Robert H. Crabtree

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