Atmospheric Chemistry and Physics, vol. 12, issue 22 (2012) pp. 10749-10758
Although oxidation of the atmospherically relevant compound alpha-pinene has been extensively studied, chemical mechanisms leading to the formation of later generation oxidation products remain poorly understood. The present work uses cyclobutyl methyl ketone (CMK) to study the oxidation mechanism of pinonic acid, an alpha-pinene reaction product, by hydroxyl radicals ((OH)-O-center dot). CMK has a similar but simpler chemical structure compared to pinonic acid. Succinic acid, 4-hydroxybutanoic acid and 4-oxobutanoic acid were identified as first generation products of CMK. These observed organic acids were compared to compounds found in secondary organic aerosol formed from the oxidation of alpha-pinene. Results suggest that 3-methyl-1,2,3-butanetricarboxylic acid (MBTCA), terpenylic acid and diaterpenylic acid acetate are first generation products of OH oxidation of pinonic acid. Therefore, there is strong evidence that (OH)-O-center dot oxidation greatly increases the oxygenation of organic compounds (e. g. monocarboxylic acid to tricarboxylic acid) through radical mechanisms, without requiring a stable intermediate. These observations cannot be explained by traditional atmospheric chemistry mechanisms.
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