Design of chiral N-triflyl phosphoramide as a strong chiral Brønsted acid and its application to asymmetric Diels-Alder reaction

  • Nakashima D
  • Yamamoto H
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Abstract

A highly reactive and acidic chiral Brønsted acid catalyst, chiral N-triflyl phosphoramide, was developed. Highly enantioselective Diels−Alder reaction of α,β-unsaturated ketone with silyloxydiene was demonstrated using this chiral Brønsted acid catalyst.

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Authors

  • Daisuke Nakashima

  • Hisashi Yamamoto

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