The determination of standard Gibbs energies of transfer of cations across the nitrobenzene/water interface using a three-phase electrode

  • Scholz F
  • Gulaboski R
  • Caban K
  • 22


    Mendeley users who have this article in their library.
  • 51


    Citations of this article.


A three-phase electrode consisting of a droplet of a nitrobenzene solution of iron(III) tetraphenyl porphyrine chloride (Fe(III)TPP-Cl) attached to a graphite electrode and immersed in an aqueous electrolyte solution was applied to determine the standard Gibbs energies of transfer of cations between water and nitrobenzene. The reduction of Fe(III)-TPP-Cl prompts the transfer of the cations from the aqueous to the organic phase. The system is chemically and electrochemically reversible. © 2003 Elsevier B.V. All rights reserved.

Author-supplied keywords

  • Cation transfer
  • Iron(III) tetraphenyl porphyrine chloride
  • Lipophilicity
  • Liquid/liquid interface
  • Three-phase electrode

Get free article suggestions today

Mendeley saves you time finding and organizing research

Sign up here
Already have an account ?Sign in

Find this document


  • Fritz Scholz

  • Rubin Gulaboski

  • Karolina Caban

Cite this document

Choose a citation style from the tabs below

Save time finding and organizing research with Mendeley

Sign up for free