Dynamic kinetic resolution of azlactones catalyzed by chiral Brønsted acids

  • Lu G
  • Birman V
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Abstract

Chiral Brønsted acids have been shown for the first time to catalyze the dynamic kinetic resolution of azlactones. 3,3'-Bis-(9-anthryl)-BINOL phosphoric acid 3c is particularly effective in the case of 4-aryl-substituted substrates, producing 85-92% ee's.

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Authors

  • Guojian Lu

  • Vladimir B. Birman

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