Abstract
(Figure Presented) Controlling guests: Porous coordination polymers containing mobile organic groups, such as naphthalene rings (see picture), are synthesized, and their rotational motion is characterized by solid-state 2H NMR spectroscopy. The rotation of the groups can be switched off (blue) by guest (blue spheres) adsorption and switched on (yellow) again by guest desorption. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
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Horike, S., Matsuda, R., Tanaka, D., Matsubara, S., Mizuno, M., Endo, K., & Kitagawa, S. (2006). Dynamic motion of building blocks in porous coordination polymers. Angewandte Chemie - International Edition, 45(43), 7226–7230. https://doi.org/10.1002/anie.200603196
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