Dynamic motion of building blocks in porous coordination polymers

  • Horike S
  • Matsuda R
  • Tanaka D
 et al. 
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Abstract

Porous coordination polymers contg. mobile org. groups, [[CdNa(2-stp)(pyz)0.5(H2O)](H2O)]n (stp = sulfoterephthalate, pyz = pyrazine) and [Zn2(1,4-ndc)22(dabco)]n (ndc = naphthalenedicarboxylate, dabco = 1,4-diazabicyclo[2.2.2]octane), were synthesized, and their rotational motion was characterized by solid-state 2H NMR spectroscopy. The rotation of the groups can be switched off by guest (benzene) adsorption and switched on again by guest desorption. [on SciFinder(R)]

Author-supplied keywords

  • cadmium pyrazine sulfoterephthalate porous coordin
  • guest adsorption desorption porous coordination po
  • zinc naphthalenedicarboxylate dabco porous coordin

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Authors

  • Satoshi Horike

  • Ryotaro Matsuda

  • Daisuke Tanaka

  • Seijiro Matsubara

  • Motohiro Mizuno

  • Kazunaka Endo

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