Effect of diazocine bridgehead modification on the folding of the wilcox molecular torsion balance: A view from a different angle

  • Bhayana B
  • Ams M
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Abstract

Replacing the methano (NCH(2)N) bridgehead with an ethano (NCH(2)CH(2)N) bridgehead affects the conformational equilibrium of the Wilcox molecular torsion balance. With a NCH(2)CH(2)N bridgehead, the phenyl and the cyclohexyl esters prefer the out conformation, whereas with the NCH(2)N bridgehead, they were found to prefer the folded conformation.

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Authors

  • Brijesh Bhayana

  • Mark R. Ams

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