Electric Polarization of Dilute Polar Solutions: Revised Treatment for Arbitrary Shaped Molecules

  • Vlassiouk I
  • Smirnov S
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Abstract

A model for deducing dipole moments of solute molecules from the electric polarization of dilute solutions is revised. The treatment represents a modified Onsager model extended toward arbitrary-shaped molecules. A simplified approach for data evaluation is suggested and compared with the analytical solution for an ellipsoidal cavity and with a numerical solution for two spherical ions.

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