Electrophilic "fischer type" phosphinidene complexes of molybdenum, tungsten, and ruthenium

  • Sterenberg B
  • Udachin K
  • Carty A
  • 9

    Readers

    Mendeley users who have this article in their library.
  • 63

    Citations

    Citations of this article.

Abstract

Chloride abstraction from chloroaminophosphido complexes of molybdenum, tungsten, and ruthenium leads to the terminal aminophosphinidene complexes [Cp*(CO)3Mo(=PNiPr2)][AlCl4] (3), [Cp*(CO)3W(=PNiPr2)][AlCl4] (4), and [Cp*Ru(CO)2(=PNiPr2)][AlCl4] (6). These are the first structurally characterized examples of heteroatom-substituted phosphinidene complexes, and 6 is the first example of a late transition metal phosphinidene complex.

Get free article suggestions today

Mendeley saves you time finding and organizing research

Sign up here
Already have an account ?Sign in

Find this document

Authors

  • Brian T. Sterenberg

  • Konstantin A. Udachin

  • Arthur J. Carty

Cite this document

Choose a citation style from the tabs below

Save time finding and organizing research with Mendeley

Sign up for free