The potential energy surface for the reaction of HOCO radicals with hydrogen atoms has been explored using the CCSD(T)/aug-cc-pVQZ ab initio method. Results show that the reaction occurs via a formic acid (HOC(O)H) intermediate, and produces two types of products: H(2)O+CO and H(2)+CO(2). Reaction enthalpies (0 K) are obtained as -102.0 kcalmol for the H(2)+CO(2) products, and -92.7 kcalmol for H(2)O+CO. Along the reaction pathways, there exists a nearly late transition state for each product channel. However, the transition states locate noticeably below the reactant asymptote. Direct ab initio dynamics calculations are also carried out for studying the kinetics of the H+HOCO reaction. At room temperature, the rate coefficient is predicted to be 1.07x10(-10)cm(3) molec(-1) s(-1) with a negligible activation energy E(a)=0.06 kcalmol, and the branching ratios are estimated to be 0.87 for H(2)+CO(2), and 0.13 for H(2)O+CO. In contrast, the product branching ratios have a strong T dependence. The branching ratio for H(2)O+CO could increase to 0.72 at T=1000 K.
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