Functional group-selective poisoning of molecular catalysts: A ruthenium cluster-catalysed highly amide-selective silane reduction that does not affect ketones or esters

  • Sasakuma H
  • Motoyama Y
  • Nagashima H
  • 26

    Readers

    Mendeley users who have this article in their library.
  • 53

    Citations

    Citations of this article.

Abstract

The addition of amines eliminates the catalytic activity of a triruthenium cluster in the hydrosilane reduction of ketones and esters without affecting the rate of reduction of amides; selective reduction of the amide group in amido ketones and amido esters is accomplished.

Get free article suggestions today

Mendeley saves you time finding and organizing research

Sign up here
Already have an account ?Sign in

Find this document

Authors

  • Hidehiro Sasakuma

  • Yukihiro Motoyama

  • Hideo Nagashima

Cite this document

Choose a citation style from the tabs below

Save time finding and organizing research with Mendeley

Sign up for free