Hetero Diels-Alder reaction of olefin with o-quinone methides generated using (±)-binolphosphoric acid for the stereoselective synthesis of 2,4-diarylbenzopyrans: Application to the formal synthesis of myristinin B/C

  • Gharpure S
  • Sathiyanarayanan A
  • Vuram P
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Abstract

Hetero Diels-Alder reaction of olefin with o-quinone methides (o-QMs) generated using (+/-)-binolphosphoric acid was developed for the stereoselective synthesis of 2{,}4-diarylbenzopyrans. The method thus developed was utilized in the formal synthesis of myristinin B/C.

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