Abstract
The framework materials [W72MnII/III12O268X7]52-/40- undergo heteroatom (X)-controlled reversible SC-SC redox reactions whereby the Ge-templated framework reduction is fast and reoxidation is slow. The opposite trend is set for the Si-templated framework, and these processes can be followed optically, spectroscopically and crystallographically. © 2009 American Chemical Society.
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CITATION STYLE
APA
Thiel, J., Ritchie, C., Streb, C., Long, D. L., & Cronin, L. (2009). Heteroatom-controlled kinetics of switchable polyoxometalate frameworks. Journal of the American Chemical Society, 131(12), 4180–4181. https://doi.org/10.1021/ja809422k
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