Reactions of heterobimetallic 3d-4f Schiff base complexes of the formula [ZnLnL(H2O)(NO3)3] (1a-e) with KOCN or NH 4SCN in refluxing MeCN produce either one dimensional polymeric materials [ZnLnL(NO3)2(H2O)(OCN)] ∞ (2a-c) or trinuclear complexes of the formula [Zn 2LnL2(NO3)(SCN)2] (3a-e) (a (La), b (Nd), c (Er), d (Tb), e (Eu); H2L = N,N′-bis-(3- methoxysalicylidene)ethylene-1,2-diamine). The structures of 2a,b and 3b-e have been determined by single-crystal X-ray diffraction studies. Structural differences between the complexes affect the photophysical properties, which have been studied in acetonitrile solutions. © The Royal Society of Chemistry 2009.
CITATION STYLE
Zhao, S., Lü, X., Hou, A., Wong, W. Y., Wong, W. K., Yang, X., & Jones, R. A. (2009). Heteronuclear trimetallic and 1D polymeric 3d-4f Schiff base complexes with OCN- and SCN- ligands. Dalton Transactions, (43), 9595–9602. https://doi.org/10.1039/b908682j
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