Iron-catalyzed Oxidative radical cross-coupling/cyclization between Phenols and Olefins

  • Huang Z
  • Jin L
  • Feng Y
 et al. 
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Abstract

Selectively free: A highly efficient and selective iron-catalyzed oxidative radical cross-coupling/cyclization to prepare dihydrobenzofurans under mild conditions had been established. Phenols and olefins are directly utilized as clean nucleophiles. Mechanistic investigations revealed that the reaction proceeds through a radical pathway, and the high selectivity is due to the Lewis acid.

Author-supplied keywords

  • cyclization
  • iron
  • olefins
  • oxidative cross-coupling
  • phenols

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Authors

  • Zhiliang Huang

  • Liqun Jin

  • Ye Feng

  • Pan Peng

  • Hong Yi

  • Aiwen Lei

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